Pesticide Fate and Transport in Rivers

Significance:

  • Neonicotinoid pesticides are ubiquitous in both urban and agricultural streams

  • Cause paralysis and death to non-target organisms, such as honeybees, through photo-transformation resulting in highly toxic byproducts

Objective:

  1. Quantify the effect of path-specific environmental conditions on photochemical transformation and rates of two important pesticides in aquatic environments. 

Hypothesis:

  • River morphology will create photochemical transformation “hotspots” impacting end-product composition of pesticides being transported in a river reach

Preliminary Conclusions:

  • Byproducts formed and degradation was slower in water with high organic matter.

  • Clothianidin exceeded chronic ecotoxicity limits in Nebraska, while imidacloprid exceeded ecotoxicity limits in North Carolina

Funded: USDA-NIFA

Publication: Borsuah, J., Messer, T.L., Snow, D., Comfort, S., and Mittelstet, A. 2020. Literature Review: Global neonicotinoid occurrence in aquatic environments. Water, 12: 3388. doi. 10.3390/w12123388.

2 additional publications In-Prep

Graduate Student: Josephus Borsuah

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Nanopesticide Implications to N Processes in Wetlands (USDA-NIFA Funded) - Coming Soon!

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N Cycle Implications in Treatment Wetlands Receiving Runoff Cocktails (NSF Funded - Coming Soon!)